Table 15.1. List of various biohybrids applied for remediation and biosensing.
Biohybrid
Pollutants
Parameters
(PPDB: The
Pesticide Properties
Database,http://
sitem.herts.ac.uk/
aeru/footprint/en/
index.htm accessed
in June 2012)
Photoelectrochemical
cell employing purple
bacterial reaction centre
Herbicides
1. Stigmatellin
2. Terbutryn
3. Atrazine
I C50 (nM)
280 60
208 10
2100 100
K i (nM)
165
123
1200
LOD (nM)
10
8.3
49
Swarming biohybrid
adsorbents/magnetic
biohybrid adsorbents
Heavy Metals
1. NI (II)
2. CO (II)
3. Mn (II)
4. Hg (II)
5. Cd (II)
6. Pb (II)
Removal
efficiency
27.3 to 48.3%
(static)
29.2 to 85.2%
(swarming)
Herbicides
1. Metolachlor
2. Phenanthreneb
3. Atrazine
4. DEA
5. DIA
Insecticides
1. Methyl Parathion
2. Malathion
3. α – Endosulfan
4. β – Endosulfan
5. Endosulfansulfate
6. Chlorpyrifos
Fungicides
1. Flutriafol
Linear range/
(µg/ml)
0.02 – 24.28
0.20 – 21.24
0.82 – 28.88
0.84 – 36.94
0.22 – 24.50
0.20 – 28.50
0.22 – 17.44
0.10 – 14.46
0.22 – 24.42
0.28 – 18.48
0.20 – 20.58
SIM ionsa
162.1, 238.0, 146.0
188.1, 189.0, 184.0
200.0, 215.0, 202.0
172.0, 187.0, 174.0
173.0, 158.0, 144.9
262.9, 108.9, 124.9
173.0, 124.9, 157.9
240.8, 194.9, 236.8
194.9, 236.8, 240.8
271.8, 273.8, 228.8
196.9, 198.9, 313.9
123.0, 164.0, 219.0
LOD
(µg/L)
0.02
-
0.03
0.06
0.17
0.12
0.03
0.06
0.03
0.08
0.03
0.06
LOQ
(µg/L)
0.02
-
0.20
0.82
0.84
0.22
0.20
0.22
0.10
0.22
0.22
0.20
P vap
c /mPa
(25 o C)
1.7
-
0.039
12.4
-
2.0
3.1
0.83
0.83
0.83
1.43
0.44
K H
d /(Pa m3 /mol)
2.40 × 10-3
-
1.50 × 10–4
1.55 × 10–4
1.52 × 10–5
8.57 × 10–3
1.00 × 10–3
1.48
1.48
1.48
4.78 × 10–1
1.27 × 10–6
K OC
e /
(mL/g)
200
-
100
72
142
240
217
11500
11500
5194
8151
205
t 1/2
f /day
90
-
75
45
-
12
0.17
50
50
-
50
1358
S w
g /(mg/L)
(20 o C)
530
-
35
3200
670
55
148
0.32
0.32
0.48
1.05
95
Biohybrid
S. lactis-silica NP
S. cerevisiae-silica NP
Metal ion
Uranium (VI)
Mercury (Hg2+ )
Removal
efficiency
92%
98%
References
Mishra et al. 2014
Shukla et al. 2020
aIons used for substance quantification (first ion) and identification (second and third ions) during the Selected Ion Monitoring (SIM); binternal standard; cPvap: vapour pressure; dKH: Henry’s
Law constant; eKOC: soil organic carbon sorption coefficient; ft1/2: half-live; gSw: water solubility -: metabolite; Pesticide Properties Database (PPDB). (Agriculture & Environment Research
Unit, University of Hertfordshire, PPDB: The Pesticide Properties Database, http://sitem.herts.ac.uk/aeru/footprint/en/index.htm accessed in June 2012.)
Biohybrids for Environmental Remediation and Biosensing 273